Chiral-and multiply-carboxylated phosphanes and phospha-method. The diphenylphosphanyl derivatives 14Ϫ16 (R, RЈ = Ph) are accessible by an alternative method involving LiAlH 4 nyl derivatives of benzoic and phthalic acids (1Ϫ9) are accessible in high yields by nucleophilic phosphanylation of potas-r
✦ LIBER ✦
ChemInform Abstract: Water Soluble Phosphanes. Part 9. Nucleophilic Phosphanylation of Fluoroaromatic Compounds with Carboxyl, Carboxymethyl, and Aminomethyl Functionalities — An Efficient Synthetic Route to Amphiphilic Arylphosphanes.
✍ Scribed by M. HINGST; M. TEPPER; O. STELZER
- Book ID
- 101867562
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
In continuation of a work to develop water-soluble phosphanes for two-phase catalysis, nucleophilic phosphanylations of potassium or lithium salts of fluoroaromatic compounds are carried out. Ligands such as (III)-(VI) and (VIII) and (X) are characterized by NMR and mass spectroscopy. -(HINGST, M.; TEPPER, M.; STELZER, O.; Eur.
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Nucleophilic Phosphanylation of Fluoroar
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Martin Hingst; Michael Tepper; Othmar Stelzer
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John Wiley and Sons
🌐
English
⚖ 654 KB