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ChemInform Abstract: Water Soluble Phosphanes. Part 9. Nucleophilic Phosphanylation of Fluoroaromatic Compounds with Carboxyl, Carboxymethyl, and Aminomethyl Functionalities — An Efficient Synthetic Route to Amphiphilic Arylphosphanes.

✍ Scribed by M. HINGST; M. TEPPER; O. STELZER


Book ID
101867562
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


In continuation of a work to develop water-soluble phosphanes for two-phase catalysis, nucleophilic phosphanylations of potassium or lithium salts of fluoroaromatic compounds are carried out. Ligands such as (III)-(VI) and (VIII) and (X) are characterized by NMR and mass spectroscopy. -(HINGST, M.; TEPPER, M.; STELZER, O.; Eur.


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Nucleophilic Phosphanylation of Fluoroar
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Chiral-and multiply-carboxylated phosphanes and phospha-method. The diphenylphosphanyl derivatives 14Ϫ16 (R, RЈ = Ph) are accessible by an alternative method involving LiAlH 4 nyl derivatives of benzoic and phthalic acids (1Ϫ9) are accessible in high yields by nucleophilic phosphanylation of potas-r