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An asymmetric conjugate addition reaction of lithium organocopper reagent controlled by a chiral amidophosphine

โœ Scribed by Motomu Kanai; Yuichi Nakagawa; Kiyoshi Tomioka

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
701 KB
Volume
55
Category
Article
ISSN
0040-4020

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๐Ÿ“œ SIMILAR VOLUMES

An external chiral amidophosphine ligand
An external chiral amidophosphine ligand for asymmetric conjugate addition of organocopper
โœ Yuichi Nakagawa; Motomu Kanai; Yasuo Nagaoka; Kiyoshi Tomioka ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 741 KB

Two types of external, chiral amidophosphine ligands, 1-5, were prepared. Examination of their behavior in an asymmetric conjugate addition reaction of organocuprate revealed the possibility for steric tuning to realize high selectivity.