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An approximate theory of the ozone isotopic effects: Rate constant ratios and pressure dependence

โœ Scribed by Gao, Yi Qin; Marcus, R. A.


Book ID
120080221
Publisher
American Institute of Physics
Year
2007
Tongue
English
Weight
484 KB
Volume
127
Category
Article
ISSN
0021-9606

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๐Ÿ“œ SIMILAR VOLUMES


The rate constant of the reaction OD+DNO
โœ Alain R. Bossard; George Paraskevopoulos; Donald L. Singleton ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 568 KB

Absolute rate constants for the reaction OD + DNOJ have been determined at 297 + 2 K, using a pulsed laser photolysis-resonance absorption technique. The values (in cm3 mol-' s-l) obtained for DN03 alone and in the presence of 107 Torr SF, and at + 3a are (5.47 zb 0.75) x lo9 and (8.51+ 0.72) x lo9

Rate constant for the OH + CO reaction:
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The effect of pressure on the rate constant of the OH + CO reaction has been measured for Ar, N,, and SF, over the pressure range 200-730 torr. All experiments were at room temperature. The method involved laser-induced fluorescence to measure steady-state OH concentrations in the 184.9 nm photolysi