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An application of N-trimethylsilylpyrroles as dienes in the Diels-Alder reaction. Synthesis of 1,4-dihydronaphthalen-1,4-imines

✍ Scribed by P.S. Anderson; M.E. Christy; G.F. Lundell; G.S. Ponticello


Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
223 KB
Volume
16
Category
Article
ISSN
0040-4039

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✦ Synopsis


Recent interest in the chemistry of 1,4-dihydronaphthalen-1,4-imines prompts this report of an extremely useful synthetic variation1 of the classical Diels-Alder approach to this ring system which was first described by Wittig.2-1'

The addition of benzyne to E-methylpyrrole is of limited synthetic utility, however, due to the instability of the product under the reaction conditions.

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