An application of N-trimethylsilylpyrroles as dienes in the Diels-Alder reaction. Synthesis of 1,4-dihydronaphthalen-1,4-imines
β Scribed by P.S. Anderson; M.E. Christy; G.F. Lundell; G.S. Ponticello
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 223 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Recent interest in the chemistry of 1,4-dihydronaphthalen-1,4-imines prompts this report of an extremely useful synthetic variation1 of the classical Diels-Alder approach to this ring system which was first described by Wittig.2-1'
The addition of benzyne to E-methylpyrrole is of limited synthetic utility, however, due to the instability of the product under the reaction conditions.
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π SIMILAR VOLUMES
The effect of side chain substituents on the Intramolecular Diels-Alder reaction of the Furan diene (IMDAF) is reported in which the side chain connecting the furan diene to the dienophile contain four carbon atoms. The synthesis of 1,4epoxycadinane