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An Answer to the Article ‘On the Misleading Interpretation of the Properties of the f-Electron Elements’

✍ Scribed by Shyama P. Sinha

Publisher
John Wiley and Sons
Year
1979
Tongue
German
Weight
221 KB
Volume
62
Category
Article
ISSN
0018-019X

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✦ Synopsis

The position of the 'Inclined W theory', i.e., the linear correlation of the properties (Pi) of the Ianthanide and the actinide ions with their ground state total orbital angular quantum numbers (L), Pi= wiL + k,, where wi and ki are the slopes and intercepts of the least squares lines, is made clear. The position of gadolinium is ambivalent, and it can be a common point for the symmetric 'Inclined W plots' or it may either belong to the second or the third tetrad depending on the system investigated. The propionate and the isobutyrate systems are used to elucidate the 'Inclined W concept'. The 'Inclined W parameters' for the solvent extraction of the lanthanides with PMBP ligand have been calculated.

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