An analysis of the conformers of 1,5-hexadiene
β Scribed by ROCQUE, BRANDON G.; GONZALES, JASON M.; SCHAEFER, HENRY F.
- Book ID
- 126519080
- Publisher
- Taylor and Francis Group
- Year
- 2002
- Tongue
- English
- Weight
- 503 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0026-8976
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π SIMILAR VOLUMES
The reaction mechanisms via the transition states of a loose chair, a loose boat, and a Dewar type for the Cope rearrangement of 1,5-hexadiene have been studied by a CiLC-IRC analysis on the basis of a complete active space self-consistent field (CASSCF) molecular orbital (MO) method. The CiLC-IRC a
## Abstract Double asymmetric dihydroxylation of 1,5βhexadiene gave in one step a mixture of the __d,l__/__meso__ tetrols 6 in a ratio of 3.4:1. From this ratio a facial selectivity of 6.65:1 for each double bond can be calculated. As a consequence of the double reaction the __d/l__ ratio can be es