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SYNTHESIS OF (±)-3-BROMOMETHYL-1,5-HEXADIENE AND (±)-3-BROMOMETHYL-3-METHYL-1,5-HEXADIENE

✍ Scribed by Bunce, Richard A.; Murray, Brian J.

Book ID
120464220
Publisher
Taylor and Francis Group
Year
1996
Tongue
English
Weight
339 KB
Volume
28
Category
Article
ISSN
0030-4948

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## Treatment of 15hexaa'ien-3-01s in acetic acid by Pd(0) [Pd(PPh&] led to l-methyl-1,3-cyclopentadienes. Cyclization is improved by the presence of catalytic amount of mfluoroacetic acid. Mechanism is discussedfrom the observed results with deuterated alcohols. The reaction of palladium complexes