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An Aluminophosphate of Molybdenum (V) with a Tunnel Structure: Cs9Mo9Al3P11O59

✍ Scribed by A. Guesdon; M.M. Borel; A. Leclaire; A. Grandin; B. Raveau

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
326 KB
Volume
114
Category
Article
ISSN
0022-4596

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πŸ“œ SIMILAR VOLUMES

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A New Series of Tungstoniobium Monophosphates with an Intersecting Tunnel Structure Closely Related to ReO3:ANb4WO9(PO4)3(A=K, Rb, Cs), KLiNb5O9(PO4)3, and KLi1βˆ’x(Nb, W)5O9(PO4)3
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A new series of tungstoniobium monophosphates, ANb 4 WO 9 (PO 4 ) 3 (A ‫؍‬ K, Rb, Cs), KLiNb 5 O 9 (PO 4 ) 3 , and KLi 1؊x (Nb, W) 5 O 9 (PO 4 ) 3 , has been synthesized. They all crystallize in the space group Pbam with a+ +15.5 A s , b+ +10.4 A s , c+ +10.5 A s . Their original intersecting channe

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A molybdenum(V) monophosphate containing lead has been synthesized for the 5rst time. This new phase Pb 3 (MoO) 3 (PO 4 ) 5 crystallizes in the Pnma space group with a ‫؍‬ 14.280( 1) A > , b ‫؍‬ 15.679(1) A > , and c ‫؍‬ 8.129(1) A > . The crystal structure was re5ned up to R ‫؍‬ 0.0406 and R w ‫؍‬

A Mo(V) Monophosphate with an Intersecti
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A new molybdenum ( \(\mathrm{V}\) ) monophosphate \(\mathrm{K}_{2} \mathrm{Mo}_{2} \mathrm{P}_{2} \mathrm{O}_{11}\) has been isolated. The single crystal \(\mathrm{X}\)-ray diffraction study of this phase has shown that it is isotypic with \(\mathrm{K}_{2} \mathrm{Nb}_{2} \mathrm{As}_{2} \mathrm{O}_