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An alternative synthesis of 3,6-di-O-methyl-D-galactose

✍ Scribed by John S. Brimacombe; Anthony J. Rollins


Book ID
108308031
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
143 KB
Volume
36
Category
Article
ISSN
0008-6215

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Synthesis of allyl and benzyl 4-O-(3,6-d
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Condensation of 2,4-di-O-acetyl-3,6-di-O-methyl-a-~glucopyranosyl bromide with either ally1 or benxyl2,4-di-0-methyl-cu+rhamnopyranoside in the presence of mercuric cyanide, followed by 0-deacetylation, gave the title oligosaccharides in excellent yields.