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An alternative pathway for the hydrolysis of epoxy ester compounds

โœ Scribed by Sarah E. Shaw; Tiziana Russo; David H. Solomon; Greg G. Qiao

Book ID
108249551
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
391 KB
Volume
47
Category
Article
ISSN
0032-3861

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๐Ÿ“œ SIMILAR VOLUMES

Enantioselective lipase-catalysed hydrol
Enantioselective lipase-catalysed hydrolysis of esters of epoxy secondary alcohols: An alternative to Sharpless oxidation
โœ Brian A Marples; Mark Rogers-Evans ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 211 KB

The enantioselectivity and yield of lipase-catalysed hydrolyses of epoxy butanoates (4) depends on R. Sharpless oxidation of the secondary allylic alcohol (8,R2=Pr) established that in the lipase-catalysed hydrolysis of (4,R2=Pr) the threo-isomer gave higher ee than the erythroisomer.