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An Alternative Method for the Preparation of 3-Alkylated-2-Cycloalken-1-Ones

โœ Scribed by Zhou, Yong Fan; Huang, Nai Zheng


Book ID
120403937
Publisher
Taylor and Francis Group
Year
1982
Tongue
English
Weight
183 KB
Volume
12
Category
Article
ISSN
0039-7911

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Highly efficient syntheses of 3-aryl-2-c
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Cycloalkenones are shown to be mesogens and can be synthesised in near quantitative yields by a convergent palladium(0)catalysed cross-coupling strategy; a 2-methyl group induces a change of phase from smectic to nematic.