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An air-stable catalyst system for the conversion of esters to alcohols

โœ Scribed by Berk, Scott C.; Buchwald, Stephen L.

Book ID
126267994
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
309 KB
Volume
57
Category
Article
ISSN
0022-3263

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Air-stable iron catalyst for the Oppenau
Air-stable iron catalyst for the Oppenauer-type oxidation of alcohols
โœ Sara A. Moyer; Timothy W. Funk ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 440 KB

An alcohol oxidation process using an air-stable iron tricarbonyl compound structurally similar to Shvo's diruthenium bridging hydride was developed. Secondary benzylic and allylic alcohols are oxidized in high yields, and evidence for an Oppenauer-type mechanism is presented.