## Abstract At bromide concentrations higher than 0.1 M, a second term must be added to the classical rate law of the bromate–bromide reaction that becomes −d[BrO~3~^−^]/d__t__ = [BrO~3~^−^][H^+^]^2^(__k__~1~[Br^−^] + __k__~2~[Br^−^]^2^). In perchloric solutions at 25°C, __k__~1~ = 2.18 dm^3^ mol^−
An adiabatic reaction calorimeter for the determination of kinetic constants of liquid reactions at high concentrations
✍ Scribed by W. Frankvoort
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 898 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-6031
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