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An ab Initio Study on [1,2] Rearrangement Reactions of Silylmethanol H 3 SiCH 2 OH

✍ Scribed by Yu, Yongming; Feng, Shengyu

Book ID
126061567
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
121 KB
Volume
108
Category
Article
ISSN
1089-5639

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The reaction of OH radicals with olefins is known to be important in atmospheric chemistry. From experimental data a global mechanism has been proposed, but the regioselectivity of the products is uncertain. In this work, the OH-propene-O 2 reaction has been studied with ab initio molecular orbital