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An ab Initio Quantum-Chemical Study of the Blue-Copper Site of Azurin

✍ Scribed by van Gastel, M.; Coremans, J. W. A.; Sommerdijk, H.; van Hemert, M. C.; Groenen, E. J. J.


Book ID
127259239
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
78 KB
Volume
124
Category
Article
ISSN
0002-7863

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We report electron-nuclear double-resonance experiments on a single crystal of azurin at 95 GHz and electron-spin-echo envelope-modulation experiments on frozen solutions of azurin and of the H117G mutant at 9 GHz. The hyperfine and quadrupole tensors of the two remote nitrogens of the histidine lig