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An ab initio and X-ray study of morpholinone derivatives: the intermolecular 1,3-dipolar cycloaddition of a derived ylide with maleimide

✍ Scribed by Michael G.B Drew; Laurence M Harwood; Gyoosoon Park; David W Price; Simon N.G Tyler; Chan Ryang Park; Soo Gyeong Cho


Book ID
108371238
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
261 KB
Volume
57
Category
Article
ISSN
0040-4020

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Structure of the Cycloaddition Products
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Investigation of the cycloaddition reaction under thermodynamic control of pyrido[2,1-a]isoindole with maleimide derivatives revealed a new rearrangement leading to 2-{2Ј-[(1R)-2,5-dioxopyrrolidinylidene]-2Ј-[(1R)-2,5-dioxopyrrolidinyl)methyl]}phenylpyridine. Their structure was confirmed by Xray di