Amplification of Enantiomeric Excess in a Proline-Mediated Reaction
โ Scribed by Suju P. Mathew; Hiroshi Iwamura; Donna G. Blackmond
- Book ID
- 101567373
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 166 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A trace amount (ca. 3 mg) of 2-methylpyrimidyl alkanol with only a slight enantiomeric excess (0.2-0.3% e.e.) was auto-multiplied with dramatic amplification of enantiomeric excess (up to ca. 90% e.e.) in one-pot asymmetric autocatalytic reaction using diisopropylzinc and 2-methylpyrimidine-5-carbal
How homochiral amino acids and sugars arose out of a presumably prochiral prebiotic environment is a puzzling question, [1] to which many answers have been proposed: for example, absolute asymmetric synthesis with circularly polarized light, photoreactions in chiral crystals, and asymmetric automult