Amphiphilic block copolymers of vinyl ethers (VES) of the type -[CH2CH(OCH,CH,0 R)]. - [CH,CH(OiBu)]n -were synthesized by living cationic polymerization, where R is a I>-glucose residue, and m and n are the degrees of polymerization (m = 20-50; n = 11-89). To obtain them, sequential living block c
Amphiphilic block copolymers with pendant thiol groups in side chains by RAFT polymerization
✍ Scribed by Hrsic, Emin; Zografou, Iason; Schulte, Bjoern; Pich, Andrij; Keul, Helmut; Möller, Martin
- Book ID
- 122549234
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 990 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0032-3861
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## Abstract Amphiphilic block polymers of vinyl ethers (VEs). \documentclass{article}\pagestyle{empty}\begin{document}$\rlap{--} [{\rm CH}\_{\rm 2} {\rm CH}\left( {{\rm OCH}\_{\rm 2} {\rm CH}\_{\rm 2} {\rm NH}\_{\rm 2} } \right)\rlap{--} ]\_m \rlap{--} [{\rm CH}\_{\rm 2} {\rm CH}\left( {{\rm OR}}
## Abstract Well‐defined amphiphilic block‐graft copolymers PCL‐__b__‐[DTC‐__co__‐(MTC‐mPEG)] with polyethylene glycol methyl ether pendant chains were designed and synthesized. First, monohydroxyl‐terminated macroinitiators PCL‐OH were prepared. Then, ring‐opening copolymerization of 2,2‐dimethylt
Amphiphilic block and statistical copolymers of vinyl ethers (VEs) with pendant glucose residues were synthesized by the living cationic polymerization of isobutyl VE (IBVE) and a VE carrying 1,2:5,6-di-O-isopropylidene-D-glucose (IpGlcVE), followed by deprotection. The block copolymer was prepared