Amphiphile Structures in the Solid State: Complex Cations with Lipophilic Substituents
β Scribed by Jack M. Harrowfield; George A. Koutsantonis; Gareth L. Nealon; Brian W. Skelton; Allan H. White
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 234 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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Solid-state complexes between para-sulphonatocalix[4]arene and a wide variety of organic cations, especially those containing amino groups are studied due to their potential applications. The structures of the complexes between para-sulphonatocalix[4]arene and norspermidine and triethyltetramine sho
Diphenyl diselenide reacts with [CpRh(CO) 2 ] (1) to give the dimer [CpRh(SePh)(l-SePh)] 2 (2), the solid state structure of which has been determined by X-ray analysis; the dimeric structure is retained in solution. In contrast, [Cp\*Rh(CO) 2 ] (4) gives the ionic product [Cp\*Rh(l-SePh) 3 RhCp\*][