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Amphenone Analogs. III. Pinacol-Pinacolone Type Rearrangement in the Pyridine Series 1

✍ Scribed by Bencze, W. L.; Allen, M. J.


Book ID
127066328
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
525 KB
Volume
81
Category
Article
ISSN
0002-7863

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acid chain was carried out in about 90% yield by catalytic hydrogenolysis of the 2-iodoethyl derivative l c which was prepared from hexamethyl dicyanocobyrinate [2] via the primary alcohol l a and the corresponding mesylate l b (cf. Exper. Part). When oxidized with O2 in the presence of ascorbic aci