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Aminotroponiminate and Aminotroponate Complexes of Group 15 (P, As) Elements: Synthesis, X-ray Diffraction Analysis and Reactivity

✍ Scribed by Lucian-Cristian Pop; Annie Castel; Luminita Silaghi-Dumitrescu; Nathalie Saffon


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
590 KB
Volume
2011
Category
Article
ISSN
1434-1948

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## Abstract Monosubstituted amidinate complexes [RC(NRβ€²)~2~]ECl~2~ [E = Sb, R = __t__Bu, Rβ€² = __i__Pr 1, Cy 2, 2,6‐__i__Pr~2~C~6~H~3~ (Dipp) 3; R = __n__Bu, Rβ€² = __i__Pr 4; E = Bi, R = __t__Bu, Rβ€² = __i__Pr 5, Dipp 6] were prepared in high yields by salt elimination reactions of ECl~3~ with Li amid