𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Aminolysis of Aryl Chlorothionoformates with Anilines in Acetonitrile: Effects of Amine Nature and Solvent on the Mechanism

✍ Scribed by Oh, Hyuck Keun; Ha, Joo Suk; Sung, Dae Dong; Lee, Ikchoon


Book ID
126844229
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
96 KB
Volume
69
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Kinetics and mechanism of the reaction o
✍ Hai Whang Lee; Arun Kanti Guha; Ikchoon Lee 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 95 KB

## Abstract The kinetics and mechanism of the nucleophilic substitution reactions of __p__‐chlorophenyl aryl chlorophosphates (2) with anilines are investigated in acetonitrile at 55°C. Relatively large magnitudes of ρ~X~ and β~X~ values are indicative of a large degree of bond making in the TS. Sm

Solvent hydrogen bonding and structural
✍ N. Kalaimani; S. Rathinam; D. S. Bhuvaneshwari 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB 👁 2 views

Substitution reactions of some parasubstituted anilines with 2-chloro-5nitropyridine and 2-bromo-5-nitropyridine were carried out conductometrically in dimethylsulfoxide/acetonitrile mixtures. The correlation of second order rate constants with Hammett's substituent constants yields a fairly linear

Reactions of aryl acetates with secondar
✍ Enrique A. Castro; Daniela Millan; Raul Aguayo; Paola R. Campodónico; José G. Sa 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB

## Abstract We report a kinetic study on the reactions of secondary alicyclic amines toward 4‐nitrophenyl, 2,4‐dinitrophenyl, and 2,4,6‐trinitrophenyl acetates (**1, 2**, and **3**) in ethanol/water mixtures of different compositions. It is found that (i) the intermediate in the reaction of **1** i