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Amino acid derived morpholine amides for nucleophilic α-amino acylation reactions: A new synthetic route to enantiopure α-amino ketones

✍ Scribed by Saumitra Sengupta; Somnath Mondal; Debasis Das

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
252 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Nucleophilic acylation reactions of amino acid derived morpholinc amides with organolithium reagents provide a new. cost-effective synthesis of enantiopure or-amino ketones.

📜 SIMILAR VOLUMES

Catalyzed reactions of α-amino diazoketo
Catalyzed reactions of α-amino diazoketones with allyl sulfides: a new synthetic protocol for α-amino homoallyl ketones en route to 3-piperidinol alkaloids
✍ Saumitra Sengupta; Somnath Mondal 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 148 KB

Cu(acac) 2 -catalyzed reactions of enantiopure α-amino diazoketones with allyl sulfides provide a facile synthetic route to α-amino homoallyl ketones via 2,3-sigmatropic rearrangements of the derived allyl sulfonium ylides.