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Amino acid-azetidine chimeras: synthesis of enantiopure 3-substituted azetidine-2-carboxylic acids

✍ Scribed by Sajjadi, Z. ;Lubell, W.D.

Book ID
110893848
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
257 KB
Volume
65
Category
Article
ISSN
1397-002X

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Enantiopure azetidine 2-carboxylic acids were prepared by hydrolysis of the corresponding 2-cyano azetidines, without ring cleavage of the azetidine or epimerization. The produced amino acids, which are conformationally constrained analogues of phenylalanine, can be cleanly debenzylated and used for