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Amide catalysts with tetradentate ligands and the asymmetric transfer hydrogenation of carbonyl compounds

✍ Scribed by Charles M Marson; Ido Schwarz

Book ID
104211170
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
73 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Amidic tetradentate catalysts comprising two trans-1,2-cyclohexanediamine units linked via a dicarbonyl spacer are shown to provide useful enantiomeric excesses in the asymmetric transfer hydrogenation from propan-2-ol to aromatic ketones. N-Benzylation of the terminal amino groups results, in several cases, in reversal of the absolute configuration of the major product.

πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Amide Catalysts wit
ChemInform Abstract: Amide Catalysts with Tetradentate Ligands and the Asymmetric Transfer Hydrogenation of Carbonyl Compounds.
✍ Charles M. Marson; Ido Schwarz πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons βš– 27 KB πŸ‘ 2 views

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