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Asymmetric Hydrogenation of Ketones with H 2 and Ruthenium Catalysts Containing Chiral Tetradentate S 2 N 2 Ligands

✍ Scribed by Patchett, Ruth; Magpantay, Iris; Saudan, Lionel; Schotes, Christoph; Mezzetti, Antonio; Santoro, Francesco


Book ID
120712535
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
551 KB
Volume
52
Category
Article
ISSN
0044-8249

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Treatment of complex trans-[RuCl(2)(eta(2)-C(2)H(4))[kappa(3)-N,N,N-(R,R)-Ph-pybox]] [(R,R)-Ph-pybox = 2,6-bis[4'-(R)-phenyloxazolin-2'-yl]pyridine] with phosphines or phosphites in dichloromethane at 50 degrees C leads to the formation of novel ruthenium(II)-pybox complexes trans-[RuCl(2)(L)[kappa(