AM1 study of the thermolysis of n-butyl-O-R
✍ Scribed by San-Guo Hong; Shen Wang
- Book ID
- 113258535
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 286 KB
- Volume
- 305
- Category
- Article
- ISSN
- 0166-1280
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## Abstract Thermal decomposition of thiones of selected N‐, O‐ and S‐heterocycles under flash vacuum thermolysis conditions was investigated. In the case of six‐membered 4__H__‐3,1‐benzoxathiin‐4‐thione **6**, the course of the reaction depended on the substitution pattern at C(2) (__Scheme 3__).
## Abstract A kinetic study of the thermolysis of 4‐crotyl‐3,5‐diphenyl‐4__H__‐1,2,4‐triazole (**1**) in a melt of the neat compound was performed at temperatures in the range of 260–350 °C. The main products formed were 1‐crotyl‐3,5‐diphenyl‐1__H__‐1,2,4‐triazole (3) and 1‐(1‐methylallyl)‐3,5‐diph