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AM1 studies of hydrogen bonded adducts between 2,5-dihydroxy-p-quinone and N-bases

✍ Scribed by Mario Bossa; Giorgio O. Morpurgo; Laura Morpurgo


Book ID
113258209
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
469 KB
Volume
330
Category
Article
ISSN
0166-1280

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Formation of Hydrogen-Bonding Adduct bet
✍ Dr. I. S. Ahmed Farag; Dr. A. M. Gad; Dr. A. M. El-Shabiny; Dr. V. B. Rybakov πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 372 KB πŸ‘ 1 views

## Abstract The adduct compound was prepared by condensation of equimolar quantities of analar vaniline and 1‐phenyl‐2‐amino pyrimidine in absolute ethyl alcohol. Prismatic crystals were obtained with the crystallographic data: __a__ = 12.901 (6), __b__ = 19.297 (9), __c__ = 6.828 (3) Γ…, Ξ³ = 102.67

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Seven crystalline N'-alkyl-N2-arylthioureas were studied by I3C CP/MAS NMR and by IR spectroscopy. The double set of signals in I3C CP/MAS spectra indicates that molecules of N'-ethyl-Nz-(3-methy1phenyl)thiourea and N'-ethyl-N2-(4-methyIphenyl)thiourea are crystallographically non-equivalent. N'-Pro