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Aluminum hydride reduction of .alpha.-ketols. II. Additional evidence for conformational flexibility in the transition state

✍ Scribed by Bowlus, Stephen B.; Katzenellenbogen, John A.


Book ID
120456715
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
794 KB
Volume
39
Category
Article
ISSN
0022-3263

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Additional Evidence for the Existence of
✍ G. L. LemiΓ¨re; T. A. van Osselaer; F. C. Alderweireldt πŸ“‚ Article πŸ“… 2010 πŸ› Wiley (John Wiley & Sons) βš– 387 KB πŸ‘ 1 views

## Abstract Only one isokinetic relation is found for the NaBH~4~ reduction of aliphatic ketones. The study includes acyclic and cyclic ketones, hindered and unhindered cyclohexanones, overall reaction rates and reaction rates of axial and equatorial attack on cyclohexanones. This strongly supports