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Additional Evidence for the Existence of Only One Kind of Transition State in the NABH4 Reduction of Aliphatic Ketones

✍ Scribed by G. L. Lemière; T. A. van Osselaer; F. C. Alderweireldt


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
387 KB
Volume
87
Category
Article
ISSN
0037-9646

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✦ Synopsis


Abstract

Only one isokinetic relation is found for the NaBH~4~ reduction of aliphatic ketones. The study includes acyclic and cyclic ketones, hindered and unhindered cyclohexanones, overall reaction rates and reaction rates of axial and equatorial attack on cyclohexanones. This strongly supports the view‐point that all these reactions proceed through only one kind of transition state. For aromatic ketones other correlations are found corresponding with other types of transition state.


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