Aluminium deposition and dissolution in aluminium chloride—n-butylpyridinium chloride melts
✍ Scribed by P.K. Lai; M. Skyllas-Kazacos
- Book ID
- 107749550
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 647 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-4686
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The kinetics of aluminium deposition from NaCI-AICl, and NaCl-KCI-AlCI, melts (cata, -=z 0.4 mol %) was studied by linear sweep ~oltammetry and potential step ampero.nctry. The reduction of AK& on tungsten and aluminium elcctrodcs was found to be diffusion controlled. The diffusion coefficients of A
The kinetics of aluminium deposition from NaCI-AICl, melts (c,,,,, < 10 mol%) contained in alumina crucibles was studied by linear sweep voltammetry and potential step amperometry at temperatures around 820°C. At low concentrations (r,,,, I c 0.4 mol %) the reduction of AlCl, on iiquid aluminium has