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Alternative synthetic path to (−)-adalinine via a SmI2-promoted fragmentation of a 3-oxopyrrolidine derivative

✍ Scribed by Toshio Honda; Chihiro Hisa

Book ID
104096659
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
322 KB
Volume
50
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Application of Sama
ChemInform Abstract: Application of Samarium Diiodide-Promoted Reductive Carbon—Nitrogen Bond Cleavage Reaction to 3-Oxopyrrolidine Derivatives: Alternative Synthesis of a Coccinellid Alkaloid, (-)-Adalinine.
✍ Toshio Honda; Chihiro Hisa 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 23 KB 👁 2 views

## Abstract The application of the samarium diiodide fragmentation reaction to 5,5‐disubstituted oxopyrrolidines (I) leads to a regioselective carbon—nitrogen bond cleavage affording the 4,4‐disubstituted cleavage products (II).