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Alternating and Non-Alternating Pd-Catalysed Co- and Terpolymerisation of Carbon Monoxide and Alkenes

✍ Scribed by Eduardo J. García Suárez; Cyril Godard; Aurora Ruiz; Carmen Claver

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
191 KB
Volume
2007
Category
Article
ISSN
1434-1948

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✦ Synopsis

Abstract

The co‐ and terpolymerisation of carbon monoxide and alkenes are usually catalysed by palladium complexes, and the properties of the produced polyketones can be finely tuned by an appropriate choice of catalyst and olefinic monomer. After a general overview of the topic, selected recent advances in this field are described. The use of palladium systems containing modified diphosphane and/or new phosphorus‐based ligands, and the results obtained using a series of modular N and S ligands, including chiral ligands, in CO/styrene co‐ and terpolymerisations are reported. The use of new P‐O ligands in non‐alternating CO/ethene copolymerisation is also described. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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