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Alteration Products of Equilenin. I. The Oxidation of Equilenin Acetate 1

✍ Scribed by McNiven, N. L.


Book ID
126223143
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
539 KB
Volume
76
Category
Article
ISSN
0002-7863

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Regioselective oxidations of equilenin d
✍ Jerry Yang; Ronald Breslow πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 90 KB

Equilenin acetate and dihydroequilenin acetate were oxidized with iodosobenzene and a rhodium(III) porphyrin catalyst. The selectivity of the reactions differs from that with the corresponding Mn(III) catalyst, or from that of free radical chain oxidation.