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Allylic rearrangement of 3,3,3-trichloro-1-propenyl ketones

โœ Scribed by Takeda, Akira.; Tsuboi, Sadao.

Book ID
126101626
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
560 KB
Volume
35
Category
Article
ISSN
0022-3263

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Allylic 1,3-rearrangement of thiophenyl
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โœ Albert Padwa; William H. Bullock; Andrew D. Dyszlewski ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 230 KB

Substituted thiophenyl ally1 sulfones undergo a 1,3-allylic sulfonyl shift and this rearrangement has been utilized within a metallation-alkylation sequence. The synthetic application of sulfones to the preparation of natural products has increased enormously during the past several years. 1~ This