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Allylic CH Oxidation versus Epoxidation of 2-Cyclohexenols, Catalyzed by Chromium- and Manganese-Substituted Polyoxometalates and Salen Complexes

✍ Scribed by Waldemar Adam; Marike Herold; Craig L. Hill; Chantu R. Saha-Möller

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
265 KB
Volume
2002
Category
Article
ISSN
1434-193X

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Enantioselective Oxidation of Secondary
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✍ Wei Sun; Xiaomei Wu; Chungu Xia 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

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Enantioselective Oxidation of Secondary
Enantioselective Oxidation of Secondary Alcohols Catalyzed by Soluble Chiral Polymeric [N′,N′-Bis(salicylidene)ethane-1,2-diaminato(2−)]manganese(III) ([MnIII(salen)]) Type Complexes in a Biphasic System
✍ Wei Sun; Xiaomei Wu; Chungu Xia 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 56 KB

## Abstract The polymeric [__N__′,__N__′‐bis(salicylidene)ethane‐1,2‐diaminato(2−)]manganese(III) ([Mn^III^(salen)]) type complexes **1** and **2** were successfully applied to the oxidative kinetic resolution of secondary alcohols. The reaction proceeded readily at room temperature with excellent