Allylic amine formation by imination of allylic tellurides
β Scribed by Yoshiaki Nishibayashi; Sanjay Kumar Srivastava; Kouichi Ohe; Sakae Uemura
- Book ID
- 103428417
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 320 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The title amines have been pyrolyzed in a stirredβflow reactor, at temperatures of 360β500Β°C, pressures of 7β16 torr, and residence times of 0.5β2.9 s, using toluene as carrier gas. The reaction products were allene, propene, and the corresponding imines. The ratio allene:propene varied
## Abstract **Regioselective, stereoselective**: The convergent coupling of allylic alcohols with imines to deliver stereodefined homoallylic amines is described (see scheme). The process proceeds with net allylic transposition without the intermediacy of allylic organometallic reagents. Two stereo