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Allylbarium in organic synthesis: unprecedented .alpha.-selective and stereospecific allylation of carbonyl compounds

โœ Scribed by Yanagisawa, Akira; Habaue, Shigeki; Yamamoto, Hisashi


Book ID
127348551
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
285 KB
Volume
113
Category
Article
ISSN
0002-7863

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Selective tin and zinc mediated allylati
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Aldehydes undergo preferentlal allyla=ion ~n the presence of ketones by che c~n or zinc mediated method, easily effected in aqueous media. Allylacions of carbonyl compounds co homoallyllc alcohols ~s an important syn~hecic pathway 2. its hlgh potential in the build-up of some natural compounds has