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Allenes and acetylenes XXVI. Organocuprate reactions of 1,3-alkadien-2-yl phosphates. a new approach to the synthesis of allenes

โœ Scribed by Alf Claesson; Abdul Quader; Christer Sahlberg


Book ID
108381875
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
176 KB
Volume
24
Category
Article
ISSN
0040-4039

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## Addition of dihalocarbenes to a diphosphene gave diphosphiranes which undergo rearrangement on treatment with alkyllithium reagents to afford 1,3-diphospha-allene; dynamic NMR studies on the allene are described.