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Alkyne and Alkene Complexes of a d 0 Zirconocene Aryl Cation

โœ Scribed by Stoebenau, Edward J.; Jordan, Richard F.


Book ID
127035740
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
54 KB
Volume
126
Category
Article
ISSN
0002-7863

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Isomerization of olefins by titanocene a
โœ A. Ohff; V.V. Burlakov; U. Rosenthal ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 690 KB

An efficient isomerization of aliphatic and cyclic olelins is achieved by using well-defined metallocene alkyne complexes as catalysts. Titanocene complexes isomerize I-alkenes to internal alkenes under mild conditions. The titanium complex was recovered quantitatively. Cyclic olcfins, e.g. cyclohex