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Alkylative Cyclization of 1,6-Enynes in Water with an Amphiphilic Resin-Supported Palladium Catalyst.

✍ Scribed by Yasushi Nakai; Tsutomu Kimura; Yasuhiro Uozumi

Publisher
John Wiley and Sons
Year
2007
Weight
20 KB
Volume
38
Category
Article
ISSN
0931-7597

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Asymmetric Suzuki–Miyaura Coupling in Wa
Asymmetric Suzuki–Miyaura Coupling in Water with a Chiral Palladium Catalyst Supported on an Amphiphilic Resin
✍ Yasuhiro Uozumi; Yutaka Matsuura; Takayasu Arakawa; Yoichi M. A. Yamada 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 391 KB 👁 2 views

## Abstract **You oughta use water**: Broad functional‐group (FG) tolerance was observed for the title coupling of aryl halides (X=Cl, Br, I) and aryl boronic acids to give biaryl compounds with up to 94 % __ee.__ The chiral imidazoindole phosphine–palladium catalyst supported on an amphiphilic pol