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Asymmetric Suzuki–Miyaura Coupling in Water with a Chiral Palladium Catalyst Supported on an Amphiphilic Resin

✍ Scribed by Yasuhiro Uozumi; Yutaka Matsuura; Takayasu Arakawa; Yoichi M. A. Yamada


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
390 KB
Volume
121
Category
Article
ISSN
0044-8249

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Asymmetric Suzuki–Miyaura Coupling in Wa
✍ Yasuhiro Uozumi; Yutaka Matsuura; Takayasu Arakawa; Yoichi M. A. Yamada 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 391 KB

## Abstract **You oughta use water**: Broad functional‐group (FG) tolerance was observed for the title coupling of aryl halides (X=Cl, Br, I) and aryl boronic acids to give biaryl compounds with up to 94 % __ee.__ The chiral imidazoindole phosphine–palladium catalyst supported on an amphiphilic pol