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Alkylation of benzene with alcohols and benzyl chloride catalyzed by ion exchange resins

โœ Scribed by E.R. Lachter; M.M. Pinto; M.R.C. Marques

Publisher
Elsevier Science
Year
1991
Weight
43 KB
Volume
15
Category
Article
ISSN
0923-1137

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โœฆ Synopsis

polymers used in the present study was between tertachloromethane and methanol on comparison of the values obtained with small molecules.

It was also made clear that membrane polarity can explain the membrane phenomena.

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The catalytic activity of gel and macroreticular ion-exchange resins (Lewatit and Amberlyst-15) was evaluated for the reaction of benzene with benzyl alcohol and benzyl chloride at 80ยฐC in the liquid phase. With benzyl chloride, the monobenzylation product, diphenylmethane, was obtained in low yield

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The dehydration of tert-butyl alcohol (TBA) in the liquid phase was studied by using an ion exchange resin, Amberlyst 15 (A15) in the H ฯฉ form. Experiments were carried out both in a semi-batch reactor and in a continuous stirred tank reactor (CSTR) with wet or dry resins. The results with the dry r