✦ LIBER ✦

Kinetic study on the dehydration of tert-butyl alcohol catalyzed by ion exchange resins

✍ Scribed by L. C. Abella; P.-A. D. Gaspillo; M. Maeda; S. Goto

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 131 KB
Volume: 31
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1999)31:12<854::aid-kin3>3.0.co;2-6

No coin nor oath required. For personal study only.

✦ Synopsis

The dehydration of tert-butyl alcohol (TBA) in the liquid phase was studied by using an ion exchange resin, Amberlyst 15 (A15) in the H ϩ form. Experiments were carried out both in a semi-batch reactor and in a continuous stirred tank reactor (CSTR) with wet or dry resins. The results with the dry resin in the semi-batch reactor were different from those with the wet resin due to the swelling of resin in the presence of water. However, the results in CSTR agreed well with those in the semi-batch reactor using the wet resin. A rate equation that considered the inhibition of water was formulated. The experimental results agreed well with the calculated ones.

📜 SIMILAR VOLUMES

Kinetics of liquid phase synthesis of te

Kinetics of liquid phase synthesis of tert-amyl methyl ether from tert-amyl alcohol and methanol catalyzed by ion exchange resin

✍ Bo-Lun Yang; Madoka Maeda; Shigeo Goto 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 178 KB 👁 1 views

Synthesis of tert-amyl methyl ether (TAME) from methanol (MeOH) and tert-amyl alcohol (TAA) in the liquid phase was studied by using an ion exchange resin, Amberlyst15 (A15) in the H ϩ form. Experiments were carried out in a stirred batch reactor under atmospheric pressure. The effects of catalyst s

Kinetic Resolution of (±)-1-Phenylbutan-

Kinetic Resolution of (±)-1-Phenylbutan-1-ol by Means of CALB-Catalyzed Aminolyses: A Study on the Role of the Amine in the Alcohol Resolution

✍ Eduardo García-Urdiales; Francisca Rebolledo; Vicente Gotor 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB