Alkylated 1,4-diazabicyclo[2.2.2]octanes: self-association, catalytic properties, and biological activity
β Scribed by Zhiltsova, E. P.; Pashirova, T. N.; Kashapov, R. R.; Gaisin, N. K.; Gnezdilov, O. I.; Lukashenko, S. S.; Voloshina, A. D.; Kulik, N. V.; Zobov, V. V.; Zakharova, L. Ya.; Konovalov, A. I.
- Book ID
- 118809906
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 312 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1573-9171
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3-Butyn-2-one condenses with itself in the presence of 0.1 molar equiv of Dabco providing 80% yield of E-3-(1-buten-3-yn-2-oxy)-buten-2-one. Substitution at the acetylene terminus prevents the condensation. However, such ketones can be condensed with terminal acetylenic ketones to provide the cross
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