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Alkyl hydroperoxide oxidation of alkanes and alkenes with a highly active Mn catalyst.

โœ Scribed by Joseph E. Sarneski; Demetrius Michos; H. Holden Thorp; Mary Didiuk; Thomas Poon; Jennifer Blewitt; Gary W. Brudvig; Robert H. Crabtree

Book ID
104225031
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
215 KB
Volume
32
Category
Article
ISSN
0040-4039

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โœ Massimiliano Forcato; William A. Nugent; Giulia Licini ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 136 KB

Catalytic oxidation of secondary amines to nitrones using alkyl hydroperoxides as primary oxidant has been demonstrated for the first time. The titanium alkoxide catalyst is protected from co-product water by the combined use of a tightly binding trialkanolamine ligand and molecular sieves. Nitrones