Alkoxy radical reactions: the isomerization of n-butoxy radicals generated from the pyrolysis of n-butyl nitrite
โ Scribed by Alan C. Baldwin; David M. Golden
- Book ID
- 107731836
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 360 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The pyrolysis of n-propyl nitrate and tert-butyl nitrite at very low pressures (VLPP technique) is reported. For the reaction n-PrON02 A nPrO + NO2 the high-pressure rate expression at 300"K, log k, (sec-l) = 16.5 -40.0 kcal/mole/2.3 RT, is derived. The reaction tert-BuONO -% tert-BuO + N O was stud
The kinetics of the reaction of OH radicals with methyl, n-propyl, and n-butyl nitrite OH + RON0products have been studied in a discharge flow system under pseudo first-order conditions. The OH radicals were generated by the reaction of H atoms with NO2 and the concentration of OH, monitored by reso
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