Alkoxy Radical Isomerization in the OH Radical-Initiated Reactions of C 4 −C 8n -Alkanes
✍ Scribed by Kwok, Eric S. C.; Arey, Janet; Atkinson, Roger
- Book ID
- 117988422
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 277 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0022-3654
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📜 SIMILAR VOLUMES
We have calculated approximate room temperature rate constants for mtramolecular hydrogen shaft rsomerizatrons of alkyd, alkovy and alkylperoxy radrcal mtermediates in photochemical smog and found that alkoxy radicals wrth 6 hydrogcns appear to undergo I,5 hydrogen shifts at ambient conditions Produ
Reactions of n-C,H,O radicals have been investigated in the temperature range 343-503 K in mixtures of O,/N, at atmospheric pressure. Flow and static experiments have been performed in quartz and Pyrex vessels of different diameters, walls passivated or not towards reactions of radicals, and product