𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Alkoxy-Directed Radical Reductions of Ketones Using Trichlorosilane

✍ Scribed by Enholm, Eric J.; Schulte, James P.


Book ID
127038062
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
37 KB
Volume
64
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Alkoxy-Directed Rad
✍ Eric J. Enholm; James P. Schulte II πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 33 KB πŸ‘ 2 views

Alkoxy-Directed Radical Reductions of Ketones Using Trichlorosilane. -A new highly diastereoselective reduction of Ξ±-hydroxy ketones with inexpensive HSiCl 3 gives predominantly anti 1,2-diols which are converted to ketals (III) and (V) for better separation of diastereomeric mixtures. Other silane

Catalytic activation of trichlorosilane
✍ Fumiaki Iwasaki; Osamu Onomura; Katsuhiko Mishima; Toshihide Maki; Yoshihiro Mat πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 262 KB

Some kinds of N-formyl cyclic amine derivatives were found to be effective activators for trichlorosilane to reduce ketones. Namely, a catalytic amount of these activators were sufficient to complete the reduction of ketones with trichlorosilane, and the reduction of ketones by trichlorosilane with