Alkoxy-Directed Radical Reductions of Ketones Using Trichlorosilane. -A new highly diastereoselective reduction of Ξ±-hydroxy ketones with inexpensive HSiCl 3 gives predominantly anti 1,2-diols which are converted to ketals (III) and (V) for better separation of diastereomeric mixtures. Other silane
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Alkoxy-Directed Radical Reductions of Ketones Using Trichlorosilane
β Scribed by Enholm, Eric J.; Schulte, James P.
- Book ID
- 127038062
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 37 KB
- Volume
- 64
- Category
- Article
- ISSN
- 0022-3263
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