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Alkenylation with lithium alkenyls. Part XI. A new synthesis of ethylenic aldehydes

โœ Scribed by Braude, E. A. ;Evans, E. A.

Book ID
121335719
Publisher
The Royal Society of Chemistry
Year
1955
Weight
369 KB
Category
Article
ISSN
0368-1769

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The acid chloride 6 provides access to 7 (R,S and S,S) which upon bromine-lithium exchange undergoes remarkably highly diastereoselective additions to aldehydes; 7 is also readily elaborated into the acetal 10.